Kinetics in Materials Science and Engineering (Hardcover)

· 제목 : Kinetics in Materials Science and Engineering (Hardcover) 
· 분류 : 외국도서 > 과학/수학/생태 > 과학 > 물리학 > 응집물질
· ISBN : 9781138732469
· 쪽수 : 612쪽

Introduction to Kinetics

Kinetics and Materials Science and Engineering

Materials Science and Engineering

Microstructure

History of Materials Science and Engineering as a Discipline

Impact of Materials Science and Engineering

This Book

Reaction Kinetics

Introduction to Kinetic Processes in Materials

Material Transport and Reaction Rates

Dissolution of NaCl and Al2O3 Contrasting Diffusion and Reaction Control

Homogeneous and Heterogeneous Reactions

Homogeneous Reaction Rates

Reaction Order

Zero Order Reaction

First Order Reaction

Example of First Order Reaction: COCl2 Decomposition

Radioactive Decay and Related Nuclear Reactions

Radiocarbon Dating

Importance of First Order Reactions in Materials

More Complex Reactions

Pseudo First Order Reactions

Second Order Reactions

Reactions that Reach Equilibrium

Parallel Reactions

Series Reactions

Higher Order Reactions

Complexity of Real Reactions: HI and H2O formation

Appendix: Two Reactions in Series

Temperature Dependence of the Reaction Rate Constant

Arrhenius Equation: k = k0 exp(-Q/RT)

Hindenburg Disaster

Adiabatic Flame Temperature

Combustion Synthesis

Barometric Formula

Boltzmann Distribution

Activated State

Catalysts: Pt, Ziegler-Natta

Heterogeneous Reactions: Gas-Solid

Passive Corrosion: SiO2

Active Corrosion: Si, Cr, SiC

Materials Processes: Kroll Process, Siemens Process, Optical Fibers, and Halogen Lamps

Chemical Vapor Deposition of Si: Deposition Processes and Epitaxy

Deposition of Silicon from Trichlorosilane

Active Gas Corrosion of Silicon

Carbon-Carbon Composites: Chemical Vapor Infiltration and Shuttle Columbia Accident

Halogen Lamps

Common Phenomena: Kinetic and Thermodynamic Factors and Growth Rate

Phase Transformations

Thermodynamics of Surfaces and Its Effects

Surface Energy: Origin and Importance

Surface Reconstruction

Typical Values

Surface Energy and Curvature

Curvature and Vapor Pressure

Curvature and Solubility

Curvature and Phase Stability

Ostwald Ripening by Reaction

Freezing Point Depression

Specific Surface Area

Wetting

Interfacial Energies and Microstructure

Interfacial Energies and Morphology

Interfacial "Phases"

Capillary Rise

Surface Segregation

Phase Transitions

Thermodynamics

Rates of Phase Transitions

Transitions in One-Component Solids

Transitions in Multi-Component Systems

Qualitative: Nucleation and Growth and Spinodal Decomposition

Quantitative: Nucleation and Growth

Nucleation Rate

Overall Rate of Phase Transformations: Johnson-Mehl-Avrami Equation

Precipitation

Crystallization of Polyethylene

Heterogeneous Nucleation

Appendix A: Kinetic Energy and Speed of Gas Molecules

Appendix B: Boltzmann Distribution

Appendix C: Maxwell-Boltzmann Speed Distribution

Appendix D: Mean Molecular Speed in a Gas

Appendix E: Exact Result for Molecular Surface Collision Rate

Appendix F: Langmuir Adsorption Isotherm

Diffusion in Ideal Systems

Introduction to Diffusion

The Diffusion Process

Fick's First Law

Values of Diffusion Coefficients: D = 1/3 λv, Gases, Solids, and Liquids

Fick's Second Law: Conservation of Mass

Solving Diffusion Problems: Boundary and Initial Conditions

Infinite and Semi-Infinite Boundary Conditions

Finite Boundary Conditions

Steady-State versus Equilibrium

Measurement of Diffusion Coefficients

Appendix A: Fick's Second Law in Cylindrical Coordinates

Appendix B: Fick's Second Law in Spherical Coordinates

Atomistic Mechanisms of Diffusion in Solids and Gases

Introduction: Magnitudes and T-Dependencies, Why Not Liquids?

Energy Absorption by Atoms and Molecules and Gases and Solids

Interstitial Diffusion in Solids

Vacancy Diffusion in Solids

Statistical Mechanics Approach: Vacancy "Concentrations"

Regular Solution Approach

Quasi-Chemical Approach: "Point Defect Chemistry"

Point Defect Charges: Kroger-Vink Notation

Intrinsic Point Defects in Compounds: Schottky Defects

Implications of Vacancy Diffusion

Intrinsic Vacancy Diffusion

Surface and Grain Boundary Diffusion

Reptation in Polymers

Diffusion in Gases

Mean Free Path in a Gas

Gas Diffusion Coefficient

Chapman-Enskog Equation

Kundsen Diffusion

Appendix A: Vibrational Frequency

Appendix B: Vacancy Concentrations for Schottky Defects, NaCl, and Al2O3

Steady-State Diffusion

Gas Diffusion through Solids

Polymer Gas Separation Membranes

Gas Diffusion through Metals

Cylindrical and Spherical Coordinates

Hydrogen Diffusion in a Glass Laser Fusion Sphere

Passive Oxidation of Silicon

Review of Glass Structure and Properties: Glass Transition and Shuttle Challenger Accident

CO2 Diffusion through a Biological Cell Wall

CVD of Si from SiHCl3 by Diffusion

CVD of Si with Both Reaction and Diffusion

Evaporation of a Water Drop

Dissolution of NaCl

Dissolution of Spheroidized Cementite in Austenite

Common Phenomena: Kinetic and Thermodynamic Factors and Growth Rate

Ostwald Ripening by Diffusion

Solutions to Fick's Second Law: Infinite and Semi-Infinite Boundary Conditions

Goal and Caveats

Solution with a Dimensionless Variable: x2 = 4 Dt

Semi-Infinite BCs: Diffusion of B into Si and Error Functions

Infinite BCs: Interdiffusion of Cu and Ni

Constant Surface Concentration: B into Si

Constant Surface Concentration: Decarburizing Transformer Steel

General Solution

Appendix A: Integrating e x2dx ∞ ? ?∞ ∫

Appendix B: Notes on the Error Function

Finite Boundary Conditions

Coring in a Cast Alloy

Drying a Cast Polymer Sheet: C(x,0) = C0 sin (πx/L)

Degassing Transformer Steel: C(x,0) = C0

Diffusion through a Polymer Membrane

Equilibration by Diffusion in a Cell

Interdiffusion of Finite Size Particles

General Approximation: Dt/L2 ? 1

Diffusion in Non-Ideal Systems

Generalized Diffusion: Fluxes and Forces

Flux of Moving Particles

Mobility and Forces: Stokes Law

Particle Size Measurement by Settling

Electrical Mobility

Absolute Mobility and Diffusion

Diffusion in Liquids: Stokes-Einstein Equation

Ionic Conductivity: Nernst-Einstein Equation

Non-Ideal Diffusion Processes

Interdiffusion in Isomorphous Systems: Metals

Intrinsic Diffusion Coefficient

Kirkendall Effect

Darken's Equations

Interdiffusion in Isomorphous Systems: Ionic Compounds

Non-Isomorphous Systems

Free Energy Gradients and Geometries

Oxidation of Metals

Calcining: Linear Model

Calcining: Jander Model

Calcining: Braunstein Model

Sintering

Grain Growth

Spinodal Decomposition Revisited