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· 분류 : 외국도서 > 기술공학 > 기술공학 > 전력자원 > 전기 에너지
· ISBN : 9781848217249
· 쪽수 : 208쪽
· 출판일 : 2018-03-09
목차
Introduction vii
Chapter 1. Anatomy of an All-Solid-State Battery 1
1.1. Constituents of an all-solid battery 3
1.1.1. Nature of solid electrolytes: required qualities 3
1.1.2. Positive electrode materials 4
1.1.3. Negative electrode materials 5
1.1.4. Conductive additive 7
1.1.5. Formulation of electrodes 7
1.2. Shaping methods of all-solid batteries 8
1.2.1. Assembly by cold pressing 8
1.2.2. Design by high temperature sintering 10
Chapter 2. Solid Ionic Conductors 13
2.1. Introduction 13
2.2. Solid lithium-ion conductors 15
2.2.1. The Garnets 15
2.2.2. The NASICON AxMM′(XO4)3 structure 17
2.2.3. The compounds LISICON and Thio-LISICON 18
2.2.4. Ion conductive glass and glass-ceramics 23
2.2.5. The Argyrodites 29
2.2.6. The complex hydrides . 34
2.2.7. Phosphorus and lithium oxynitride or LiPON 36
2.2.8. Anti-perovskite lithium-rich solid electrolytes 36
2.2.9. Solid polymer electrolytes 39
2.3. Solid sodium-ion conductors 40
2.3.1. NASICON compounds 41
2.3.2. Na3PS4 42
Chapter 3. All-Solid-State Battery Technology Using Solid Sulfide Electrolytes 47
3.1. Monolithic Li-ion “all-solid-state” batteries 47
3.1.1. The first “all-solid-state” batteries 47
3.1.2. Second generation “all-solid-state” batteries 48
3.1.3. Toward High Performance Batteries 53
3.1.4. Batteries using lithium argyrodite electrolytes 58
3.1.5. Li10XP2S12 (X = Ge, Si, Sn) phase in the structure LGPS 66
3.1.6. Understanding stability at the interfaces between the electrolyte and electrode materials 81
3.1.7. Summary 84
3.2. Sodium monolithic “all-solid-state” batteries 85
3.3. “All-solid-state” Li–S batteries 91
Chapter 4. Monolithic “All-Solid-State” Batteries Using Solid Oxide Electrolytes 97
4.1. Silver “all-solid-state” battery technology 97
4.2. Li-ion “solid-state” battery technology 100
4.3. Sodium “solid-state” battery technology 108
4.3.1. Sodium-ion “solid-state” battery technology 108
4.3.2. Sodium-sulfur “all-solid-state” battery technology 116
Chapter 5. LiBH4 Electrolyte and Polymer Battery Technology 119
5.1. “All-solid-state” battery technology: LiBH4 electrolyte 119
5.2. “Solid-state” polymer battery technology 120
Chapter 6. Markets 123
6.1. Solid electrolytes 123
6.1.1. Ohara 123
6.1.2. NEI 127
6.2. Solid-state batteries 127
6.3 Conclusion 137
Conclusion 139
Bibliography 145
Index 167
