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Raman Spectroscopy in Cultural Heritage Preservation

Raman Spectroscopy in Cultural Heritage Preservation (Hardcover)

Howell G. M. Edwards, Philippe Colomban, Peter Vandenabeele (지은이)
Springer
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Raman Spectroscopy in Cultural Heritage Preservation
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· 제목 : Raman Spectroscopy in Cultural Heritage Preservation (Hardcover) 
· 분류 : 외국도서 > 과학/수학/생태 > 과학 > 분광학/광선분석
· ISBN : 9783031143786
· 쪽수 : 493쪽
· 출판일 : 2022-10-14

목차

Chapter 1: Foreword

Chapter 2: Historical Overview

2.1. References

Chapter 3: Theory and Understanding

3.1. History

3.2. The Raman Effect

3.3. Instrumentation

3.4. Understanding and Assignment of Raman Spectral Signatures

3.4.1. Peak Wavenumbers and Assignment

3.4.2. Peak Intensity and Assignment

3.4.3. Molecular and Physical Description of Vibrational Modes

3.4.4. Implication for Spatial Resolution

3.4.5. Symmetry and Peak Numbers

3.4.6. Laser Choice and Resonance Effects

3.4.7. Raman Tensors and Polarization

3.4.8. Background subtraction

3.5. Databases; Advantages and drawbacks

3.6. References

Chapter 4: Combination of RS and Other Techniques

4.1. Optical Microscopy and the First RM

4.2. Scanning and Transmission EM

4.3. Castaing Microprobe

4.4. Other Couplings

4.5. References

Chapter 5: Pigments, Dyes and Coloured Agents

5.1. Arts and Colours

5.2. Raman Determination of Coloured Agents

5.3. Coloured Agents , Dyes and Pigments

5.4. From Alchemy to Chemical Industry

5.5. Advantages and Drawbacks of Raman Microscopy

5.5.1. Smalt or Lapis Lazuli ?

5.5.2. Natural or Synthetic Ultramarine

5.5.3. High Detectivity

5.5.4. Elimination of Wrong Conclusions from EA

5.5.5. Identification of Organic Dyes

5.6. Non-destructive and Non-invasive Procedures

5.7. SERS and Associated Techniques

5.8. Data treatment

5.9. Degradation and Conservation

5.10, Dating

5.11 References

Chapter 6: Cultural Heritage Meets Art Forensics

6.1. Introduction

6.2. Case Study 1 : Disappearing Amber

6.3. Case Study 2 : Cat with Enigmatic Smile

6.4. Case Study 3 : Ming Porcelain

6.5. Case Study 4 : Analysis Baffles Expert Opinion

6.6. Case Study 5 : Insect Trapped in Amber

6.7. Summary

6.8. References

Chapter 7: Jewellery and Gemstones

7.1. Introduction

7.2. Phase identification and Characterisation

7.3. Provenance Studies

7.4. Distinguishing gems from Glass and Fakes

7.5. Modern Synthetic gems

7.6. Case Studies

7.6.1. Jade

7.6.2. Corals, Pearls, Mother of Pearl

7.6.3. Ivory

7.6.4. Ambers and Natural Resins

7.7. On site Spectroscopy of Gems

7.8. References

Chapter 8: Cave Paintings and Rock Art

8.1. Introduction

8.2. Rock Art and Cave Sites Studied by Raman Spectroscopy

8.3. Information from Raman Spectral Data for Cultural Heritage Preservation

8.4. References

Chapter 9: From Frescoes to Paintings

9.1 Efficiency of Raman Microscopy

9.2. Procedures and Artefacts

9.3. Pigments and Dyes

9.4. Examples of Procedures: Measurements at the Laboratory and On-Site

9.5. Colour Fading and Degradation

9.6. Conclusions

9.7. References

Chapter 10 : Analytical Raman Spectroscopy of Manuscripts and Maps : The Role of Inks

10.1. Introduction

10.2. Origin and Composition of Carbon Black and Iron Gall Inks

10.3. Iron Gall Ink and Manuscript Deterioration

10.4. Coloured Inks

10.5. The Deterioration of Ancient Inks

10.6. Case Studies

10.6.1. The Vinland Map

10.6.2. The Beato de Valcavado Manuscript

10.6.3. The Cercelli Gospels and the Gospel of Judas

10.7. Conclusions

10.8 References

Chapter 11 : Patina , Corrosion and Conservation Treatment

11.1. Mechanisms of Corrosion and Patination

11.2. Patinas and Their Raman Signatures

11.3. Stability Towards Corrosion

11.3.1. Iron-Based Artefacts

11.3.2. Stones and Buildings

11.3.3. Glass

11.4. Conservation Treatment

11.5. Perspectives

11.6. References

Chapter 12 : Glass , Pottery , Enamelled Artefacts

12.1. Introduction

12.2. XO4 vibrations and the Raman Signatures Of Crystalline and glassy Silicates

12.2.1. Structure and Raman Signature Relationship

12.3. The Different Glass Compositions : A Brief Historical Survey

12.4. Glass Raman Fingerprint and Resonance Raman Effect

12.5. Glass Weathering , Dating and Conservation

12.6. Mobile Raman Spectroscopy

12.7. Multivariate Analysis

12.8. Recognising Technology Milestones : Tracing the Exchanges and Case Studies

12.8.1. Blue and Green Glass Coloured with Lapis Lazuli

12.8.2. Yellow and Green Colours

12.8.3. Trade Glass Beads

12.9 References

Chapter 13 : Archaeology of Biomaterials : Mummies , Ivories, Resins and Textiles

13.1. Introduction

13.2. Archaeological Specimens I : Mummies and Skeletal Remains

13.2.1. Mummified Tissues

13.2.1.1. Tomb of the Two Brothers

13.2.1.2. Otzi, the Alpine Ice-Man

13.2.1.3. The Qilakitsoq and Chiribaya Ice Mummies

13.2.1.4. The Beni Hassan Cat Mummy

13.2.1.5. The Antarctic Emperor Penguin Mummy

13.2.2. Human Skeletal Remains

13.2.2.1. The Anglesey Dark Ages Cist Burial

13.2.2.2. Gristhorpe Man

13.2.2.3. A Sambaqui Burial and Ochred Bones

13.2.2.4. A Change of Coffin : Analytical Spectral Information from Hair

13.3. Archaeological Specimens II : Functional or Decorative Items

13.3.1. Ivories

13.3.2. Resins, Gums, Waxes

13.3.2.1. Ambers and Copals

13.3.2.2. Dragon’s Blood

13.3.2.3. Frankincense , Myrrh and Pine Resins

13.3.2.4. Contents of Chests from Marine Excavations

13.4. Textiles

13.4.1. The HMS Victory Sail

13.4.2. Mummy Linens

13.5. Conclusions

13.6. References

Chapter 14 : Raman Spectroscopy and Industrial Archaeology

14.1. Introduction

14.2. The Role of Analytical Chemistry

14.3. Raman Spectroscopy and the Analysis of Industrial Archaeology

14.3.1. Abandoned Mine of a Previously Indeterminate Purpose

14.3.2. Unexpected Hazards in Mines (St Joachimstahl and St Austell )

14.3.3. Nantgarw China Works Waste Pit

14.4. The Use of Portable Raman Spectroscopic Instrumentation

14.5. References

Chapter 15 : Raman Spectroscopic Analysis of a Putative Century Oil Painting Depicting William Shakespeare

15.1. Introduction

15.2. Experimental

15.3. Results of the Raman Spectroscopic Analysis of the Pigments

15.4. Interpretation of the Raman Spectral Data

15.5. Conclusions

15.6. References

Chapter 16 : “Noli Me Tangere” : A renaissance Original ? A Holistic Analytical Spectroscopic Challenge.

16.1. Introduction

16.2. Compositional Study of the Works of Art on a “Noli Me Tangere” Theme

16.2.1. Historical Basis of the Artworks

16.2.2. The Nine Works of Art Comprising this Comparative Study

16.2.3. compositional Details Under Consideration

16.3. Results and Conclusions

16.4. References

Chapter 17 : A Case Study. Raman Spectroscopic Analysis Of Welsh Porcelains

17.1. Introduction

17.2. Experimental

17.2.1. Specimens

17.2.2. Spectroscopic Instrumentation

17.2.3. Previous Analytical Work

17.3 . Results and Discussion

17.3.1. Nantgarw and Swansea Porcelains : Statements for Verification

17.3.2. Porcelain Body Chemistry in the Kiln

17.3.3. Nantgarw 200 Porcelain

17.3.4. Raman Spectroscopic Results

17.3.4.1. Summary of Analytical Results on Nantgarw Porcelain Porcelains

17.4. References

Chapter 18 : Case Study : In-Field and On-Site Raman Spectroscopic Analysis

18.1. Why On-Site Analysis?

18.2. Instrumental Requirements and On-Site Procedures

18.3. The Role of Optics

18.4. Stand-Off Raman Spectroscopy

18.5. Protection from Ambient Light

18.6. Examples and Perspectives

18.7. References

Chapter 19: Case Study : Non-Invasively Documenting the Transfer of Enamelling Technology form Europe to China and Japan. The role of the Jesuits in the 17th Century

19.1. The Quest for Chinese Porcelain

19.2. The Response of European Potters

19.3. The European and Chinese Technologies of Enamelling

19.4. The Jesuit Missions in Japan and China

19.5. The Contribution of Raman Microscopy

19.6. Raman Identification of European Recipes /Ingredients In Chinese Cloisonees and Painted Enamel Wares

19.7. Application to Chinese Productions

19.8. Conclusions and Perspectives

19.9. References

Chapter 20: Case Study : The Shroud of Turin - Iconic Relic or Fake ? The Role of Raman spectroscopic Analysis in its Forensic Appraisal

20.1. Introduction

20.2. The Early Scientific Evidence Relating to the Turin Shroud

20.3. Recent Scientific Studies of the Turin Shroud Materials

20.4. Raman Spectroscopy and the Shroud of Turin

20.5. References

Chapter 21: Case Study : A Unique Rockingham English Porcelain Table . A Holistic Forensic Analysis.

21.1. The Rockingham Porcelain Manufactory

21.2. Analyses of Rockingham Porcelain

21.3. Raman Spectroscopic Analysis of the Porcelain Table Top

21.3.1. Background History of Wentworth Castle

21.4. Conclusions

21.5. References

Chapter 22: A Little Knowledge is Dangerous Thing. A Miscellany of Faux-Pas in the Cultural Heritage Of Literature

22.1. Preface

22.2. Introduction

22.3. Classical Literature in Cultural Heritage

22.3.1. Wilkie Collins ? Armadale

22.3.1.1. Literary Background

22.3.2. Charles Dickens - A Tale of Two Cities

22.3.3. Ross King ? Ex-Libris

22.3.4. Anthony Horowitz ? The house of Silk . The New Sherlock Holmes Novel.

22.3.5. Agatha Christie ? Various Novels

22.4. References

Chapter 23: Raman Analysis: What is Straightforward, What is Difficult and Future Perspectives.

Glossary

List of Acronyms

Index

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