Synthesis and Technique in Inorganic Chemistry (Paperback, 3, Revised)

Introduction
Safety
Laboratory Procedures
Research Notebook
Standard References
Part I. Solid State Chemistry
Experiment 1--High-Temperature Synthesis of the Superconductor YBa2Cu3O7Tube Furnace Preparation
Superconductivity
Iodometric Titrations
Experiment 2--The Layered Solids VOPO4(H2O)2 and VO(HPO4)(H2O)0.5Powder X-Ray Diffraction
Oxidation of Alcohols to Ketones
Experiment 3--The Molecular Sieve Zeolite-XSol-gel Synthesis
High Pressure Synthesis
Ion Exchange in Microporous Solids
Part II. Main Group Chemistry
Experiment 4--The Borane-Amine Adduct BH3NH2C(CH3)3Lewis Acids and Bases
Experiment 5--Buckminsterfullerene, C60, and Its ElectrochemistrySoxhlet Extraction
Cyclic Voltammetry
Experiment 6--Vacuum-Line Synthesis of GeH4Vacuum Line and Trap-to-Trap Purification
Vapor Pressure and Molecular Weight Determination of a Volatile Compound
Gas Phase IR Spectroscopy
Experiment 7--Tin Chemistry: Coordination Complexes and Organometallic DerivativesNMR Spectroscopy
Linkage Isomerism
Experiment 8--Synthesis of (C6H5)2PCH2CH2P(C6H5)2 in Liquid Ammonia
Synthesis in Liquid Ammonia
Experiment 9--Electrolytic Synthesis of K2S2O8Electrolytic Preparation
Part III. Coordination Chemistry
Experiment 10--Ion Exchange Separation of Chromium Complexes
Ion Exchange Chromatography
Experiment 11--Metal-Metal Quadruple Bonds
Molecular Orbital Theory
Experiment 12--The Magnetic Susceptibility of Mn(acac)3Magnetism of Transition Metal Complexes
The Gouy Method
The Evans MethodsExperiment 13--Cobalt Ammines and their Ligand Substitution KineticsConductivity of Ionic Complexes
Kinetics of Aquation of [Co(NH3)5Cl]2+
Experiment 14--Optical Resolution of Co(en)33+Separation of Diastereomers by Crystallization
Optical Rotations
Suction Filtration
Experiment 15--Metal Dithiolenes and the Use of Quaternary Ammonium Salts
Quaternary Ammonium Salts
Part IV. Organometallic Chemistry
Experiment 16--The Metal-Arene Complex [1,3,5-C6H3(CH3)3]Mo(CO)3IR Spectra of Metal Carbonyls
Experiment 17--Organo-iron Chemistry: (C5H5)2Fe2(CO)4 and (C5H5)Fe(CO)2(CH3)Schlenk Line Synthesis
Infrared Spectra of Solutions
Experiment 18--The Metal Carbonyl Cluster Fe3(CO)12Mass Spectrometry
Experiment 19--Microscale Synthesis of Vaska's Complex
Microscale Synthesis
Solid State IR Spectra
Experiment 20--The Air-Sensitive Sandwich Complex Nickelocene
Glove Bag Manipulations
Sublimation
Part V. Bioinorganic Chemistry
Experiment 21--Cobaloximes: Models of Vitamin-B12 Coenzymes
Enzyme Models
Experiment 22--Amino Acid Complexes: Stability Constants of Ni(glycinate)n(2 - n)+Amino Acid ChemistrypH TitrationspKa and Successive Stability Constant Determination
Experiment 23--Bioinorganic Coordination Chemistry: Copper (II) Tetraphenylporphyrinate
Porphyrin Chemistry
Thin-Layer Chromatography
Column Chromatography
Notes to the Instructor
Appendices
NMR and Mass Spectra
Index