Undergraduate Instrumental Analysis (Hardcover, 7)

Concepts of Instrumental Analytical Chemistry
Introduction: What is Analytical Chemistry?
Analytical Approach
Basic Statistics and Data Handling
Sample Preparation
Performing the Measurement
Assessing the Data
Problems
Bibliography

Introduction to Spectroscopy
Interaction Between Electromagnetic Radiation and Matter
Atoms and Atomic Spectroscopy
Molecules and Molecular Spectroscopy
Absorption Laws
Methods of Calibration
Optical Systems Used in Spectroscopy
Spectroscopic Technique and Instrument Nomenclature
Suggested experiments
Problems
Bibliography

Magnetic Resonance Spectroscopy
Nuclear Magnetic Resonance Spectroscopy Introduction
The FTNMR Experiment
Chemical Shifts
Spin?Spin Coupling
Instrumentation
Analytical Applications of NMR
Hyphenated NMR Techniques
NMR Imaging and MRI
Time Domain NMR
Low-Field, Portable, and Miniature NMR Instruments
Limitations of NMR
Electron Spin Resonance Spectroscopy
Suggested Experiments
Problems
Spectral Databases
Bibliography

Infrared, Near-Infrared, and Raman Spectroscopy
Absorption of IR Radiation by Molecules
IR Instrumentation
Sampling Techniques
FTIR Microscopy
Nondispersive IR Systems
Analytical Applications of IR Spectroscopy
NIR Spectroscopy
Raman Spectroscopy
Chemical Imaging Using NIR, IR, and Raman Spectroscopy
Suggested Experiments
Problems
Bibliography
Spectral Databases

Visible and Ultraviolet Molecular Spectroscopy
Introduction
Instrumentation
UV Absorption Spectra of Molecules
UV Spectra and the Structure of Organic Molecules
Analytical Applications
Accuracy and Precision in UV/Vis Absorption Spectrometry
Nephelometry and Turbidimetry
Molecular Emission Spectrometry
Instrumentation for Luminescence Measurements
Analytical Applications of Luminescence
Suggested Experiments
Problems
Bibliography

Atomic Absorption Spectrometry
Absorption of Radiant Energy by Atoms
Instrumentation
Atomization Process
Interferences in AAS
Analytical Applications of AAS
Suggested Experiments
Problems
Appendices
Bibliography

Atomic Emission Spectroscopy
Flame Atomic Emission Spectroscopy
Atomic OES
Plasma Emission Spectroscopy
GD Emission Spectrometry
AFS
Commercial Atomic Emission Systems
Laser-Induced Breakdown Spectroscopy
Atomic Emission Literature and Resources
Comparison of Atomic Spectroscopic and ICP-MS Techniques
Suggested experiments
Problems
Appendices
Bibliography

X-Ray Spectroscopy (Contributing authors: Alexander Seyfarth and Eileen Skelly Frame)
Origin of X-Ray Spectra
X-Ray Fluorescence
X-Ray Absorption
X-Ray Diffraction
X-Ray Emission
Commercial X-Ray Instrument Manufacturers
Suggested Experiments
Problems
Appendices
Bibliography

Mass Spectrometry I: Principles and Instrumentation
Principles of MS
Instrumentation
Ion Mobility Spectrometry
Problems
Bibliography

Mass Spectrometry II: Spectral Interpretation and Applications
Interpretation of Mass Spectra: Structural Determination of Simple Molecules
Mass Spectral Interpretation: Some Examples
Applications of Molecular MS
Atomic MS
Problems
Appendix
Bibliography

Principles of Chromatography
Introduction to Chromatography
What is the Chromatographic Process?
Chromatography in More than One Dimension
Visualization of the Chromatographic Process at the Molecular Level: Analogy to "People on a Moving Belt Slideway"
Digression on the Central Role of Silicon?Oxygen Compounds in Chromatography
Basic Equations Describing Chromatographic Separations
How Do Column Variables Affect Efficiency (Plate Height)?
Practical Optimization of Chromatographic Separations
Extra-Column Band Broadening Effects
Qualitative Chromatography: Analyte Identification
Quantitative Measurements in Chromatography
Examples of Chromatographic Calculations
Problems
Bibliography

Gas Chromatography
Historical Development of GC: The First Chromatographic Instrumentation
Advances in GC Leading to Present-Day Instrumentation
GC Instrument Component Design (Injectors)
GC Instrument Component Design (The Column)
GC Instrument Operation (Column Dimensions and Elution Values)
GC Instrument Operation (Column Temperature and Elution Values)
GC Instrument Component Design (Detectors)
Hyphenated GC Techniques (GC-MS, GC-IR, GC-GC, or D-GC)
Retention Indices (A Generalization of Relative R_t Information)
Scope of GC Analyses
Problems
Appendix 12.1
Bibliography

Chromatography with Liquid Mobile Phases
High-Performance Liquid Chromatography
Chromatography of Ions Dissolved in Liquids
Affinity Chromatography
Size-Exclusion Chromatography
Supercritical Fluid Chromatography
Electrophoresis
Planar Chromatography and Planar Electrophoresis
Problems and Exercises
Appendix 13.A
Bibliography

Surface Analysis
Introduction
Electron Spectroscopy Techniques
Ion Scattering Spectroscopy
Secondary Ion Mass Spectrometry
Electron Microprobe (Electron Probe Microanalysis)
Problems
Bibliography

Electroanalytical Chemistry
Fundamentals of Electrochemistry
Electrochemical Cells
Electroanalytical Methods
Liquid Chromatography Detectors
Spectroelectrochemistry
Quartz Crystal Microbalance
Suggested Experiments
Problems
Appendix 15.A
Bibliography

Thermal Analysis
Thermogravimetry
Differential Thermal Analysis
Differential Scanning Calorimetry
Hyphenated Techniques
Thermometric Titrimetry
Direct Injection Enthalpimetry
Microcalorimetry
Thermomechanical Analysis and Dynamic Mechanical Analysis
Optical Thermal Analysis
Summary
Suggested Experiments
Problems
Bibliography

Acronyms Index
Index