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· 분류 : 외국도서 > 과학/수학/생태 > 과학 > 화학 > 유기화학
· ISBN : 9783527306169
· 쪽수 : 1234쪽
· 출판일 : 2003-10-17
목차
Preface.
CATALYST DEVELOPMENTS.
Introduction.
The Role of the "Tebbe Complex" in Olefin Metathesis.
The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes for Alkene Metathesis.
From ill-defined to well-defined W alkylidene complexes.
Discovery of Well-defined Ruthenium Olefin Metathesis Catalysts.
Synthesis of Ruthenium Carbene Complexes.
ynthesis of Rhodium and Ruthenium Carbene Complexes with a 16-Electron Count.
Mechanism of Ruthenium-Catalyzed Olefin Metathesis Reactions.
Intrinsic Reactivity of Ruthenium Carbenes.
The Discovery and Development of High Oxidation State Alkylidyne Complexes for Alkyne Metathesis
.Well-defined Metallocarbenes and Metallocarbynes Supported on Oxide Support prepared via Surface Organometallic Chemistry
.APPLICATIONS IN ORGANIC SYNTHESIS.
Introduction.
General Ring-Closing Metathesis.
Catalytic Asymmetric Olefin Metathesis.
Tandem RCM.
Ene-Yne Metathesis.
Ring Opening Cross Metathesis.
Ring Expansion Metathesis Reactions.
Olefin Cross-Metathesis.
The Olefin Metathesis Reaction in Complex Molecule Construction.
Applications of Ring Closing Metathesis to Alkaloid Synthesis.
Radicicol and the Epothilones: Total Synthesis of Novel Anti Cancer Agents Using Ring Closing Metathesis.
The Use of Olefin Metathesis in Combinatorial Chemistry: Supported and Chromatography-Free Syntheses.
Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres.
Alkyne Metathesis.
Metathesis of silicon-containing olefins.
Commercial Applications of Ruthenium Metathesis Processes.
POLYMER SYNTHESIS.
Introduction.
Living Ring-Opening Olefin Metathesis Polymerization.
Synthesis of Copolymers.
Conjugated polymers.
Stereochemistry of ROMP.
Syntheses and Applications of Bioactive Polymers Generated by the Ring-Opening Metathesis Polymerization (ROMP).
Metathesis Polymerization: A Versatile Tool for the Synthesis of Surface-Functionalized Supports and Monolithic Materials.
Telechelic Polymers from Olefin Metathesis Methodologies.
ADMET Polymerization.
Acyclic Diyne Metathesis Utilizing in Situ Transition Metal Catalysts: An Efficient Access to Alkyne-Bridged Polymers.
Polymerization of Substituted Acetylenes.
Commercial Applications.
