재료열역학

I. 서론

II. 열역학 제 1, 2, 3 법칙

III. 상태, 상태변수 그리고 프로세스

IV. 기체의 거동
IV-1 Boyle-Charles Gas Law
IV-2 van der Waals Equation
IV-3 Internal Energies of Ideal Gas and Real Gas

V. 상태 변화 과정과 열용량
V-1 Processes of Ideal Gas
i) 등체적과정 (Constant Volume Process)
ii) 등압과정 (Constant Pressure Process)
iii) 단열과정 (Adiabatic Process)
iv) 등온과정 (Isothermal Process)
V-2 Heat Capacity
V-3 Enthalpy, H
V-4 Temperature Change during an Adiabatic Process

VI. 엔트로피의 통계역학적 해석
VI-1 Definition of Entropy S
VI-2 Statistical Interpretation of Entropy
VI-3 Thermal Entropy and Configurational Entropy
VI-4 Boltzmann Distribution Function
VI-5 Proof of lnΩ being proportional to Clausius Entropy S

VII. 가역과정과 비가역과정
VII-1 Irreversible Process
VII-2 Entropy of Irreversible Processes

VIII. 보조함수
VIII-1 Geometric Relations
VIII-2 Auxiliary Functions
(1) Enthalpy
(2) Helmholtz Free Energy
(3) Gibbs Free Energy
VIII-3 Differentials of Auxiliary Functions
VIII-4 Maxwell Relations
VIII-5 Applications of Maxwell Relation using Experimentally determined Parameters

IX. 엔탈피와 엔트로피 함수 그리고 Gibbs 자유에너지
IX-1 Enthalpy as a function of Temperature under a constant Pressure
IX-2 Entropy as a function of Temperature under a constant Pressure
IX-3 Gibbs Free Energy as a function of Temperature under a constant Pressure
IX-4 Phase Diagram determined from Gibbs Free Energy Change with Temperature and Pressure
IX-5 Clapeyron Equation
IX-6 Clausius-Clapeyron Equation

X. 기체의 거동
X-1 Temperature Variation by Heat Transfer under constant Pressure
X-2 Pressure Variation by Work Transfer under constant Temperature
X-3 van der Waals Gas Model describing Real Gas Behavior

XI. 혼합 기체의 거동
XI-1 Gibbs Free Energy Variation with Pressure under constant Temperature
XI-2 Mixture of Ideal Gases
XI-3 Partial Molar Quantities and their Physical Meanings
XI-4 Chemical Potential as a Partial Molar Quantities
XI-5 Equilibrium Vapor Pressure of a Component in Condensed Solutions
XI-6 Activity and Activity Coefficient
XI-7 Raoult's Law and Henry's Law
XI-8 Chemical Potential and Activity

XII. 화학반응 평형
XII-1 Reactions involving Gases
XII-2 Effect of Temperature on Chemical Reaction Equilibrium
XII-3 Reference Pressure and Effect of Total Pressure on Chemical Reactions
XII-4 Reactions involving Pure Condensed Phases and a Gaseous Phase
(1) CO/CO2 비율 조절을 이용한 산소분압 조절
(2) H2/H2O 비율 조절을 이용한 산소분압 조절
XII-5 Reactions involving Condensed Solution Phases and a Gaseous Phase

XIII. 상태도
XIII-1 Free Energy Change as a Solute dissolving into a Matrix
XIII-2 Gibbs Free Energy of a Binary System
XIII-3 Ideal Solution
XIII-4 Development of Phase Diagrams
XIII-5 Development of Eutectic Phase Diagrams
XIII-6 Development of Other Phase Diagrams

XIV. 용액모델
XIV-1 Non-ideal Mixing
XIV-2 Regular Solution Model

XV. 전기화학
XV-1 Ionization Energy of an Element
XV-2 Equilibrium in Two Phase Systems involving an Electrolyte
XV-3 Equilibrium in an Electrochemical Cell
XV-4 Standard Hydrogen Electrode
XV-5 Pourbaix Diagram
(1) The Stability of Water
(2) Pourbaix Diagram for Copper